Processing-structure-property relationships in solid-state shear
Solid-state shear pulverization (SSSP) is a unique processing technique for mechanochemical modification of polymers, compatibilization of polymer blends, and exfoliation and dispersion of fillers ...
Effects of Polymer Properties on Solid-State Shear …
ABSTRACT: Solid-state shear pulverization (SSSP) is an alter-native polymer processing technique based on twin-screw extrusion with a continuous cooling system. In SSSP, …
Novel synthesis of branched polypropylene via solid-state …
We describe the discovery of a novel approach to prepare LCB PP by subjecting linear PP to solid-state shear pulverization (SSSP) with benzoyl peroxide …
Solid-State Shear Pulverization: A Comprehensive Study on …
Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been shown to impart beneficial properties onto homopolymers or create copolymers and composites through continuous fragmentation and fusion. The unique technology employs cold …
Processing-structure-property relationships in solid-state …
Solid-state shear pulverization (SSSP) is a unique processing technique for mechanochemical modification of polymers, compatibilization of polymer blends, and …
Polymer
The solid-state shear pulverization (SSSP) is used to produce polymer-graphite nanocomposites that are not subject to the thermodynamic/ kinetic limitations associated with conventional processes. The polymer-graphite nanocomposite hybrids are made from chemically or thermally pretreated graphite, e.g., graphite oxide, expanded graphite, or ...
Stabilization of Dispersed Phase to Static Coarsening
Solid-state mechanochemistry technologies such as solidstate shear pulverization (SSSP), 20−22 solid-state shear extrusion (S 3 E), 23,24 and ball milling 25 have been successfully developed for ...
FLAX FIBER-POLYAMIDE 6 COMPOSITES VIA SOLID-STATE SHEAR PULVERIZATION
A chilled twin-screw extruder-based processing technique called solid-state shear pulverization (SSSP) explores an opportunity to create a new set of composites made from temperature-sensitive natural fibers and hightemperature melting thermoplastics. Model polyamide 6/ flax fiber composites produced with SSSP are compared to those made by …
Achievement of quasi-nanostructured polymer blends by solid-state shear
Here we employ solid-state shear pulverization (SSSP), a continuous, industrially scalable process that involves the use of equipment resembling a modified twin-screw extruder but with processing at room temperature or below. During SSSP, the polymer is exposed to high compressive and shearing forces, resulting in repeated …
Effects of Polymer Properties on Solid-State Shear …
This paper conducts a systematic processing-structure-property relationship investigation of 10 thermoplastic polymers with varying properties, as they are subjected …
Achievement of quasi-nanostructured polymer blends by solid-state shear
Solid-state shear pulverization (SSSP) using a batch-type kneader was performed at a temperature lower than the PP melting point in order to improve the dispersion of the LCNFs in the PP matrix ...
Production of thermoplastic starch and poly (butylene …
A novel processing technique involving Solid-State Shear Pulverization (SSSP) was used to produce thermoplastic starch (TPS) and Poly (Butylene Adipate-co-Terephthalate) (PBAT) films to improve processability and produce well-dispersed blends. Four different compositions (50-80 wt% TPS content) were processed using two …
Mechanochemical modification of crosslinked low …
This study investigates solid-state shear pulverization (SSSP) as a continuous, commercially viable mechanochemical processing technique to initiate the decrosslinking of XLLDPE for mechanical recycling. Post-industrial XLLDPE scrap material was processed using SSSP with a range of pulverization conditions, which were correlated with universal
Overcoming sustainability and energy challenges in polymer …
Solid-state shear pulverization (SSSP) is an innovative, continuous, environmentally benign, and industrially scalable process used to make materials that cannot be made via conventional processing techniques, reduce material cost by eliminating processing steps, and/or produce materials with superior properties as a result of better break-up and …
Solid‐state shear pulverization of post‐industrial …
Solid-state shear pulverization (SSSP) is a continuous, twin-screw extruder-based processing technique in which the low-temperature application of shear and compressive forces impart …
Solid-state shear pulverization as a real-world process for …
Solid-state shear pulverization (SSSP) is an innovative processing technique that has proven to effectively disperse nanoscale structural entities to achieve compatibilized …
SSSP
Solid-state shear pulverization (SSSP) is a novel mechanical process that uses a modified twin-screw extruder with cooling zones to maintain the polymer in the solid …
Solid-State Shear Pulverization
Solid-State Shear Pulverization is an innovative process that produces polymeric powders with unique physical properties not found in the output of conventional size-reduction methods. This technology has profound implications for both the creation of new polymer blends and recycling of plastic and rubber waste. Illustrated with 60 photographs, …
Green polypropylene/waste paper composites with
Solid-state shear pulverization (SSSP) is a continuous process that overcomes challenges in producing well-dispersed polymer composites that cannot be made by twin-screw melt extrusion. We use SSSP to produce 85/15 wt% polypropylene/waste paper biocomposites with polypropylene pellets and 2-cm-square …
Effects of Polymer Properties on Solid-State Shear …
This study demonstrates the promise of solid-state shear pulverization (SSSP) for making well-dispersed nanocomposites and the promise of ARG for yielding major improvement …
Solid-State Shear Pulverization: A Comprehensive Study on …
Solid-state shear pulverization (SSSP) is a continuous and scalable processing technique that imposes mechanochemical changes in polymer-based materials. It has been …
Polylactic Acid Chemical ing Assisted by Solid-State …
A chemical ing process of polylactic acid (PLA) was developed via the solid-state processing methods of solid-state shear pulverization (SSSP) and cryogenic milling. Based on the ability of solid-state processing to enhance the crystallization kinetics of PLA, chemical ing agents (CFA) are first compounded before ing via …
Solid‐state shear pulverization of post‐industrial
Solid-state shear pulverization (SSSP) is a unique processing technique for mechanochemical modification of polymers, compatibilization of polymer blends, and exfoliation and dispersion of fillers ...
Residence Time Distribution and Specific Mechanical Energy in Solid …
Solid‐state shear pulverization (SSSP) is a continuous polymer processing methodology based on a modified twin‐screw extruder. The unique application of low barrel temperatures and ...
Processing‐structure‐property relationships in solid‐state shear
Solid-state shear pulverization (SSSP) is a unique processing technique for mechanochemical modification of polymers, compatibilization of polymer blends, and exfoliation and dispersion of fillers in polymer nanocomposites. A systematic parametric study of the SSSP technique is conducted to elucidate the detailed mechanism of the …
Well-mixed blends of HDPE and ultrahigh
Here, we present solid-state shear pulverization (SSSP) as a mild, continuous, and simple approach for achieving effective and intimate mixing in UHMWPE/HDPE blends. These SSSP blends are easily processed by post-SSSP melt extrusion; for an SSSP blend with 50 wt% UHMWPE, we observe more than a factor of 1000 increase in viscosity at a …
Polymer/multiwall carbon nanotube (MWCNT) nanocomposites made by solid
Masuda, J, Kasimatis, KG & Torkelson, JM 2008, Polymer/multiwall carbon nanotube (MWCNT) nanocomposites made by solid-state shear pulverization (SSSP): Processing, dispersion and properties. in Society of Plastics Engineers - 66th Annual Technical Conference of the Society of Plastics Engineers, Plastics Encounter at ANTEC 2008. …
Polylactic Acid Chemical ing Assisted by Solid …
In previous studies, an alternative processing method called solid-state shear pul-verization (SSSP) has shown promising results in increasing the crystallization kinetics of PLA [25–27], which is considered key for better control of the cell structure [2]. ... Solid-State Shear Pulverization and Cryogenic Milling ...
Achievement of quasi-nanostructured polymer blends by solid-state shear
Achievement of quasi-nanostructured polymer blends by solid-state shear pulverization and compatibilization by gradient copolymer addition. Ying Tao, Jungki ... industrially scalable, mechanical process called solid-state shear pulverization (SSSP). An 80/20 wt% polystyrene (PS)/poly(methyl methacrylate) (PMMA) blend processed by SSSP and ...
Low-Temperature Compounding of Flax Fibers with …
Solid-state shear pulverization (SSSP) is a developing technique for processing homopolymers, polymer blends, and polymer composites and nanocomposites that uses a modified TSE in a chilled, solid-state setting [38-46]. It applies shear and compression at temperatures well below T. m, T. g
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